AP Chemistry Summer Assignment 2010.rtf
AP CHEMISTRY FIRST DAY TEST
The first day, you will have a test covering two things: 1.) Memorizing the information listed later in this document. 2.) stoichiometry calculations from the summer homework (Ch. 3). You must pass with at least 60% in order to remain enrolled in AP Chemistry. For the test, you will need to solve problems WITHOUT looking at the following material:
-
Rules for Naming Acids
-
Rules for Naming Ionic Compounds
-
Solubility Rules Group
-
Group 1A, 2A, 5A, 6A and 7A Ions
-
Variable Valences for Transition Metals
-
Polyatomic Ions (including name, symbol and charge)
-
Metric prefixes and units
- Prefixes for naming covalent compounds
AP Chemistry is a difficult course. It is not all about memorization; however, having these items memorized is essential for success in learning the concepts covered in the course.
If this seems like too much work for the summer, please drop the course. Advanced Placement Chemistry is a college level course. You will need to be dedicated and work very hard if you are to be successful.
Example test
1. Name these chemicals:
a. HCl b. H2SO4 c. HNO2 d. Ba(OH)2 e. SnO2 f. NO2
2. Write the formula of these chemicals:
a. Disulfur pentoxide
b. Tin (II) selenate
c. Iron (II) thiocyanate
d. Phosphoric acid
3. Is ammonium carbonate soluble or insoluble in water?
4. Convert 2 ng to grams.
5. DDT (C14H9Cl5), an insecticide harmful to fish, birds, and humans can be produced by reacting chlorobenzene (C6H5Cl) with chloral (C2HOCl3). The unbalanced chemical equation is:
C6H5Cl + C2HOCl3 --> C14H9Cl5 + H2O
If 922 grams chlorobenzene react with 477 grams chloral, determine:
a. The limiting reactant.
b. The theoretical yield of DDT in grams.
c. The percent yield of DDT, if the actual yield of DDT is 198.0 grams.
Example Test Answer Key
Rules for Naming and Acid
When the name of the anion ends in –ide, the acid name begins with the prefix hydro-, the stem of the anion has the suffix –ic and it is followed by the word acid.
-ide becomes hydro _____ic Acid
Cl- is the Chloride ion so HCl = hydrochloric acid
When the anion name ends in –ite, the acid name is the stem of the anion with the suffix –ous, followed by the word acid.
-ite becomes ______ous Acid
ClO2- is the Chlorite ion so HClO2 = Chlorous acid.
When the anion name ends in –ate, the acid name is the stem of the anion with the suffix –ic, followed by the word acid.
-ate becomes ______ic Acid
ClO3- is the Chlorate ion so HClO3 = Chloric acid.
Rules for naming Ionic Compounds
-
Balance Charges (charges should equal zero)
-
Cation is always written first (in name and in formula)
-
Change the ending of the anion to -ide
Solubility Rules
- All compounds containing alkali metal cations and the ammonium ion are soluble.
- All compounds containing NO3-, ClO4-, ClO3-, and C2H3O2- anions are soluble.
- All chlorides, bromides, and iodides are soluble except those containing Ag+, Pb2+, or Hg2+.
- All sulfates are soluble except those containing Hg2+, Pb2+, Sr2+, Ca2+, or Ba2+.
- All hydroxides are insoluble except compounds of the alkali metals, Ca2+, Sr2+,and Ba2+.
- All compounds containing PO43-, S2-, CO32-, and SO32- ions are insoluble except those that also contain alkali metals or NH4+.
Group 1A, 2A, 4A, 5A, 6A Ions
Group |
1A |
2A |
4A |
5A |
6A |
Ion formed |
+1 |
+2 |
-3 |
-2 |
-1 |
|
Li |
Be |
N |
O |
F |
|
Na |
Mg |
|
S |
Cl |
|
K |
Ca |
|
|
Br |
|
Rb |
Sr |
|
|
I |
|
Cs |
Ba |
|
|
|
|
Fr |
Ra |
|
|
|
Variable Valences For Transition Metals
Name
|
Symbol
|
Charge
|
Stock Name
|
---|
Chromium
|
Cr
|
+2
+3
|
Chromium (II)
Chromium (III)
|
Manganese
|
Mn
|
+2
+3
|
Manganese (II)
Manganese (III)
|
Iron
|
Fe
|
+2
+3
|
Iron (II)
Iron (III)
|
Cobalt
|
Co
|
+2
+3
|
Cobalt (II)
Cobalt (III)
|
Copper
|
Cu
|
+1
+2
|
Copper (I)
Copper (II)
|
Lead
|
Pb
|
+2
+4
|
Lead (II)
Lead (IV)
|
Mercury
|
Hg
|
+1
+2
|
Mercury (I)
Mercury (II)
|
Tin
|
Sn
|
+2
+4
|
Tin (II)
Tin (IV)
|
Gold
|
Au
|
+1
+3
|
Gold (I)
Gold (III)
|
Silver
|
Ag
|
+1
+2(rarely)
|
Silver
Silver (II)
|
Bismuth
|
Bi
|
+3
+5
|
Bismuth (III)
Bismuth (V)
|
Antimony
|
Sb
|
+3
+5
|
Antimony (III)
Antimony (V)
|
Cadmium
|
Cd
|
+2
|
Cadmium
|
Zinc
|
Zn
|
+2
|
Zinc
|
Return to Top
Polyatomic Ions
Name
|
Symbol
|
Charge
|
ammonium
|
NH4
|
+1
|
acetate
|
C2H3O2
|
-1
|
bromate
|
BrO3
|
-1
|
chlorate
|
ClO3
|
-1
|
chlorite
|
ClO2
|
-1
|
cyanide
|
CN
|
-1
|
dihydrogen phosphate
|
H2PO4
|
-1
|
hypochlorite
|
ClO
|
-1
|
hydrogencarbonate(bicarbonate)
|
HCO3
|
-1
|
hydrogen sulfate (bisulfate)
|
HSO4
|
-1
|
hydrogen sulfite (bisulfite)
|
HSO3
|
-1
|
hydroxide
|
OH
|
-1
|
iodate
|
IO3
|
-1
|
nitrate
|
NO3
|
-1
|
nitrite
|
NO2
|
-1
|
perchlorate
|
ClO4
|
-1
|
permanganate
|
MnO4
|
-1
|
thiocyanate
|
SCN
|
-1
|
carbonate
|
CO3
|
-2
|
chromate
|
CrO4
|
-2
|
dichromate
|
Cr2O7
|
-2
|
oxalate
|
C2O4
|
-2
|
selenate
|
SeO4
|
-2
|
silicate
|
SiO3
|
-2
|
sulfate
|
SO4
|
-2
|
sulfite
|
SO3
|
-2
|
phosphate
|
PO4
|
-3
|
phosphite
|
PO3
|
-3
|
*The above charts taken from: Marcan, Susan P. "Advanced Placement Chemistry." Burlingame High School home page. Online. May 7, 2010.
Metric prefixes
prefix
|
abbreviation
|
meaning
|
power of ten
|
mega
|
M
|
1,000,000
|
106
|
kilo
|
k
|
1,000
|
103
|
deci
|
d
|
0.1
|
10-1
|
centi
|
c
|
0.01
|
10-2
|
milli
|
m
|
0.001
|
10-3
|
micro
|
μ
|
0.000 0001
|
10–6
|
nano
|
n
|
0.000 000 001
|
10–9
|
Metric Units
Base unit
|
abbreviation
|
quantity measured
|
meter
|
m
|
length
|
liter
|
L
|
volume
|
gram
|
g
|
mass
|
Prefixes for naming covalent compounds
Number of atoms |
Prefix |
1 |
mono |
2 |
di |
3 |
tri |
4 |
tetra |
5 |
penta |
6 |
hexa |
7 |
hepta |
8 |
octa |
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